Wellenfunktionen des Wasserstoffs

Wie sehen nun die Wellenfunktionen des Wasserstoffs aus? Im vorangegangenen Abschnitt haben Sie ψ100(r, θ, φ) bestimmt:

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Hier folgen weitere Wellenfunktionen des Wasserstoffs:

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Die Wellenfunktion ψnlm(r, θ, φ) verhält sich für kleine r wie rl und geht somit gegen null. Für große r fällt ψ100(r, θ, φ) exponentiell gegen null. Sie haben also das obige Problem gelöst, in dem die Wellenfunktion für große r divergierte. Das verdanken Sie alles der Quantisierungsbedingung, die den Ausdruck für f(r) von einer Exponentialfunktion auf ein Polynom endlicher Ordnung reduziert hat.

Abbildung 10.2 zeigt eine Darstellung der radialen Wellenfunktion R10(r); in Abbildung 10.3 ist R20(r) gezeigt; in Abbildung 10.4 schließlich können Sie R21(r) sehen.

 

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Abbildung 10.2: Die radiale Wellenfunktion R10(r)

 

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Abbildung 10.3: Die radiale Wellenfunktion R20(r)

 

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Abbildung 10.4: Die radiale Wellenfunktion R21(r)

Quantenphysik für Dummies
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